CHEMISTRY ESSAY
FOOD PRESERVATION

Food Bowl

Why Food Preservation? | Causes of Food Spoilage | Priorities of Food Preservation | Techniques of Food Preservation
Why Food Preservation?
Most of our food is perishable, and after it is harvested, it has to be transported over a long distance to the consumers. During this period, the food can be subjected to many hazardous conditions, resulting in spoilage of food or toxins harmful to humans. It has been estimated that over 10 to 20 % of our food is wasted due to food spoilage. Food preservation is the means to extend the shelf life of the food over weeks or months, and to retard or eliminate the process of decomposition.
Causes of Food Spoilage
Senescence | Chemical Deterioration | Microbiological Decay
Senescence
All foods are still living organisms to some degree and they are still respiring. Hence they can no longer effectively maintain their integrity because there are no more nutrients supply. The tissues would begin to be deteriorated. Thus, senescence occurs, in which the food would soften, darken in colour and rot.
Chemical Deterioration
After the food is harvested or slaughtered, the enzymes present are still active and are able to catalyze reactions, which could adversely affect the quality of food. These enzymatic reactions are often rapid and cause significant deterioration. For example, keeping corn at room temperature causes the sugar to be converted to starch, the desirable sweetness is thus lost.

Handling food sometimes allow contact of some natural chemicals which results in deterioration. Rancidity is one of the examples.

Microbiological Decay
Of all the decay mechanisms, microbial growth is the foremost cause of food spoilage because they multiply very quickly in room conditions. They require water, warmth, oxygen and nutrients to grow and multiply. Also, some microorganisms known as pathogens can cause diseases easily.

There are millions of microorganisms living all around us. They are very tiny organisms that we can't see with our naked eye. We notice their presence only where many of them collect together. For example, the molds on bread and the slime formation on fresh meat.

Links:
FACTORS AFFECTING MICROBIAL GROWTH
The Latest Word on Mold
Priorities of Food Preservation
  • destroy any decay or pathogenic organisms present in food
  • eliminate and control both natural and added chemical toxins
  • maintain the nutritive value in food
  • maintain original characteristic and quality of food in terms of flavour, odour, appearance and texture
Techniques of Food Preservation
Heat Preservation | Cold Preservation | Dehydration | Chemical Preservation | Irradiation | Packaging
Heat Preservation: Canning, Pasteurization & UHT
Heating the foodstuffs can destroy the spoilage and pathogenic organisms that may be present. It also inactivates the enzymes present.
Canning
Food Cans
In commercial canning, carefully prepared raw food is placed in a sealed container, subjected to definite elevated temperatures for the proper period of time, and finally cooled. Reinfection through exposure to air is prevented by the can's permanent seal. The heat requirements of canning depends on the acidity of the foodstuffs, the size of the can and the physical nature of the food.
The nutrients in canned foods are usually retained. However, vitamin C may be destroyed at elevated temperatures during the process.

Modern tin cans composed of 98.5 % of sheet steel with a thin coating of tin. Bulged ends may be caused by microbial, chemical or physical actions. Such cans may progress through various stages of swelling and finally explode.

Links:
Canning Basics
Canning Basics for Preserving Food
The Complete Guide to Home Canning
Beginner's Guide to Home Canning
Home Canning - Who & Why?
How long will canned food keep?
Pasteurization of milk
Milk is such a rich source of nutrients that it is an ideal medium for the growth of microorganisms. To kill the microorganisms present, milk is heated to at least 72 oC for at least 15 seconds, and then rapidly cooled to below 10 oC. The microorganisms are either killed or inactivated by the processes. However, pasteurization causes a slight change in flavour and nutritional value.

UHT Sterilization of milk
Ultra-high temperature (UHT) sterilization is carried out before the milk is bottled. The milk is first homogenized and it is then heated to above 132 oC for 1 to 3 seconds by flowing over a heated surface. A completely sterile product is thus obtained after cooling. It is safe and can be kept for considerable periods, with retention of its flavour and vitamins content.

Pasteurized Milk
Cold Preservation: Refrigeration & Freezing
Storage at low temperature prolongs food life by decreasing the respiration and metabolic rates of most spoilage and pathogenic microorganisms hence they cannot grow.
Food Temperature (?#060;/font>F) Food Temperature (?#060;/font>F)
Butter
Cheese (cream)
Cheese (soft)
Condensed Milk (bulk)
Cream (fresh)
Margarine
Milk (fresh)
Milk (evaporated)
Fish (fresh)
Fish (dried)
34
30-36
32-36
35-40
32-35
32-35
32-35
36-40
32
35-40
Oysters
Beer
Chocolate
Cider
Honey
Maple Syrup
Molasses
Olive Oil
Sauerkraut
Wine
32-34
32-40
38-42
32-36
40-45
40-45
40-45
35-40
34-38
40-45
Recommended Cold-Storage Temperatures for Some Selected Foods
Refrigeration
The life of many foods may be increased by storage at temperatures below 4 oC because activities of microorganisms and enzymes are much reduced. In general, for every 10 oC lowering of temperature, shelf life increases by 2 - 5 times.
Refrigerator Refrigeration cannot improve the quality of decayed foods, but only retard deterioration. It does, however, afford substantial protection against carbohydrate loss. Dehydration of foodstuffs due to moisture condensation can also be overcome through humidity control within the storage chamber and by appropriate packaging techniques.
Links:
REFRIGERATION AND FOOD SAFETY
Freezing
Freezing is a very effective mean of food preservation, as most microorganisms cannot grow at temperatures below 0 oC. Microorganisms become inactive at about -10 oC while enzymes are largely inactivated below -18 oC. It is the most efficient preservation method for many fatty foods. Freezing also destroys certain parasites in food and prevents insect infestations. The water present is frozen to ice, which is then unavailable to microorganisms and reaction. Usually, shelf life can be increased by 3 - 40 times for every 10 oC lowering.
Freezer
Freezing of food usually occurs at temperatures between -4 oC and 0 oC. It does not destroy nutrients and produce little change in the nutritive value of protein. However, repeated freezing and thawing may alter food appearance and quality. Some oxidation and destruction of vitamins may occur during freezing.

Some very juicy foods like strawberries and melons suffer from extensive drip and consequent loss of vitamin C during thawing.

Links:
Freezing Basics
Refreezing Food
Dehydration
Dehydrator
Dehydration is an effective means of inhibiting microbial growth. Very few microorganisms can grow in food with less than 5 % moisture. It is the preservation method most frequently applied to fruits. Loss of moisture content by drying resulted in the increased concentration of nutrients in the remaining food mass, and the nutritive value of most reconstituted or rehydration foods are comparable to that of fresh items. However, the vitamin level would be less satisfactory.
Foodstuffs may be dried in air, superheated steam, vacuum, inert air or by direct application of heat. Air is the most generally used drying medium, because it is plentiful and convenient, and permits gradual drying, allowing sufficient control to avoid overheating that might result in scorching and discolouration.

A modern development of dehydration is freeze-drying in which frozen foods is dried under high vacuum. It maintains the food at the best level for successful dehydration and satisfactory rehydration, with substantial retention of nutrients, colour, flavour and texture characteristics.

Links:
Drying Food
Food Drying
Quality for Keeps - Drying Foods
DRYING FOOD AT HOME
WHEN IS FOOD DRY?
Freeze drying
Chemical Preservation: Pickling, Smoking & Sugaring
Chemical food preservatives are substances which, under certain conditions, either delay the growth of microorganisms or prevent deterioration of quality. Chemical preservatives can be natural food constituents, or any food additives like antioxidants, antibiotics, blanching agents, acidulants, neutralizers, stabilizers, firming agents and humectants.
Permitted Preservative Examples of Use
E200 sorbic acid soft drinks, fruit yogurt, processed cheese
E201 sodium sorbate
E202 potassium sorbate
E203 calcium sorbate
frozen pizza, flour, confectionery
E210 benzoic acid
E211 sodium bezoate
E212 potassium benzoate
E213 calcium bezoate
E214 ethyl 4-hydroxybenzoate
E215 sodium ethyl 4-hydroxybenzoate
E216 propyl 4-hydroxybenzoate
E217 sodium propyl 4-hydroxybenzoate
E218 methyl 4-hydroxybenzoate
E219 sodium methyl 4-hydroxybenzoate
beer, jam, salad cream, soft drinks, fruit pulp, fruit-based pie fillings, marinated herring and mackerel
E220 sulphur dioxide
E221 sodium sulphite
E222 sodium hydrogen sulphite
E223 sodium metabisulphite
E224 potassium metabisulphite
E226 calcium sulphite
E227 calcium hydrogen sulphite
dried fruit, dehydrated vegetables, fruit juices and syrups, sausages, fruit-based dairy products, cider, beer and wine, to prevent browning of raw peeled potatoes and to condition biscuit dough
E230 diphenyl
E231 2-hydroxydiphenyl
E232 sodium 2-phenylphenate
surface treatment of citrus fruits
E233 thiabendazole surface treatment of bananas
E234 nisin cheese, clotted cream
E239 hexamine marinated herring and mackerel
E249 potassium nitrite
E250 sodium nitrite
E251 potassium nitrate
E252 sodium nitrate
bacon, ham, cured meats, corned beef and some cheeses
E280 propionic acid
E281 sodium propionate
E282 calcium propionate
E293 potassium propionate
bread and flour, confectionery, christmas pudding
Permitted Preservatives by the Preservatives in Food Regulations (1979)
Links:
FOOD PRESERVATION WITH CHEMICALS
Uses and effects of main food additives
Fresh Look at Food Preservatives
Antioxidants
Blanching
Pickling
Most fresh fruits and green vegetables can be preserved by pickling. Salt is added to suppress undesirable microbial activity, creating a favourable environment for the desired fermentation. Pickles can also be prepared by adding vinegar, sweat spice, herb and spices. Pathogens generally do not grow below pH 4.6. Meat and fish may also be preserved by curing or pickling. The ingredients used are sodium nitrite, sodium chloride, sugar, citric acid or vinegar.
Pickling Bottles
Links:
Quick Process Pickles
Equipment for Pickling
Vinegar for Pickling
SALTING FISH
Smoking
Smoke acts as a dehydrating agent and coats the meat surfaces with various chemicals. Bacon, ham and corned beef are examples of smoked foods. However, it has been identified that some organic compounds in smoke are known to be carcinogenic.
Sugaring
Concentrated solution of sugar is added, to a point where microbial spoilage cannot occur. Water available for enzymatic action and microbial growth is removed by osmosis. It can be used in making jams, jellies, marmalades and candying fruits.
Links:
Jams & Jellies
Osmosis
Irradiation
Certain radioactive isotopes emit electromagnetic radiation called gamma-rays, which are extremely effective in killing microorganisms. Gamma-rays are able to penetrate food to a considerable depth. Consequently, food can be processed in bulk without fearing that the innermost parts will not be properly processed. Radiation prolongs storage lives and destroys parasites, food-poisoning organisms and insects.

Sterilization of foods by irradiation requires only one-fiftieth of the energy needed for thermal sterilization. It permits sterilization of substances with a negligible temperature rise of only about 3 oC.

However, it produces widespread chemical changes in irradiated materials. Enzymes are resistant to irradiation, and they must be inactivated by other means in complement to the irradiation action. Nutrients are somewhat reduced and development of protective methods requires further study. In the early 1980s, the safety of foods treated by irradiation was still the subject of testing and evaluation.

Links:
Food Irradiation
Radiation Pasteurization of Food
PRESERVATION BY RADIATION
Advantages and Disadvantages of Using Food Irradiation
Packaging
Package
Packaging is also important in food preservation because it controls the environment inside the package so as to maintain shelf life and protects the food from being contaminated by spoilage microbes, pathogenic organisms or external chemicals. It also prevents the transport of moisture and oxygen across the barrier, loss of odours and physical damage.
Opaque packaging prevents light from reaching the food, which accelerate lipid oxidation and destroy vitamins.
Written By
Joanna Chung (12)
L6Sc
7 - 2000
Glossary

References
  • ¡mFood Science, Nutrition and Health¡n (fifth edition)
    • by Brian A Fox & Allan G Cameron
  • ¡mFood Science and Nutritional Health : An Introduction¡n
    • by Theodore P. Labuza & John W. Erdman, Jr.